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2024 04 v.39 289-304
激发态质子转移的机制探究及其性质调控
基金项目(Foundation): 国家自然科学基金资助项目(12404300)
邮箱(Email):
DOI:
中文作者单位:

辽宁大学物理学院;

摘要(Abstract):

激发态质子转移(Excited State Proton Trafmfer, ESPT)是一种重要的光诱导质子转移过程,在有机发光材料、环境监测以及生物体系中的光信号传导等领域起着至关重要作用。本文综述了ESPT的基本原理及其在不同条件下的行为。本文首先介绍ESPT的概念及种类,包括单质子转移、双质子转移以及多质子转移等。然后详细地讨论影响和调控ESPT反应的多个因素,包括溶剂效应、电场影响、取代基团效应、π扩展效应和基团位置,以及这些因素如何作用于激发态质子转移的动力学和热力学过程。通过对这些影响因素的综合分析,为理解和调控ESPT提供了深入的见解,这对于开发新型光功能材料等方面具有指导意义。

关键词(KeyWords): 激发态质子转移;荧光特性;机制探究;性质调控
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基本信息:

DOI:

中图分类号:O642.1;O643.1

引用信息:

[1]庄洪斌,乔田田,石薇等.激发态质子转移的机制探究及其性质调控[J].山东师范大学学报(自然科学版),2024,39(04):289-304.

基金信息:

国家自然科学基金资助项目(12404300)

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