山东师范大学学报(自然科学版)

2025, 04, v.40 325-351

共价有机框架材料用于光合成H_2O₂研究进展

基金项目(Foundation): 国家自然科学基金资助项目(22171169)

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摘要：

过氧化氢(H_2O₂)作为一种重要的环保氧化剂，在漂白、消毒、废水处理和化学合成中得到了广泛的应用，传统蒽醌法合成H_2O₂普遍存在高能耗、高污染等问题。利用H_2O和O₂为原料，在特定光催化剂条件下通过人工光合作用合成H_2O₂具有清洁、安全和可持续等特点，近年来得到了越来越多的关注和研究。共价有机框架(COFs)是一类新兴的晶态有机多孔材料，因其结构多样性和可调性、高比表面积以及优异的半导体特性等优点，近年来COFs材料用于光催化合成H_2O₂的应用研究得到了蓬勃发展，取得了一系列突破进展。本文系统总结和讨论了COFs材料在光合成H_2O₂领域中的最新研究进展。首先，简要介绍了COFs材料及其用于光合成H_2O₂的基本原理；然后详细综述和探讨了提高光催化性能的主要策略和方法；此外，本文还讨论和总结了COFs基光催化剂在可见光驱动H_2O₂生产中的挑战和前景。

关键词： 共价有机框架材料; 光催化; 过氧化氢;

Abstract：

Hydrogen peroxide(H_2O₂), as an important environmentally friendly oxidant, has been widely used in bleaching, disinfection, wastewater treatment, and chemical synthesis. However, the traditional anthraquinone process for H_2O₂ production suffers from high energy consumption and significant pollution issues.In recent years, the artificial photosynthesis of H_2O₂ from H_2O and O₂ over certain photocatalyst has been considered as a clean, safe, and sustainable approach and has been widely explored. Covalent organic frameworks(COFs), as an emerging class of crystalline porous organic materials, have witnessed rapid development and breakthrough advancements in photocatalytic H_2O₂ synthesis owing to their structural diversity and tunability, high specific surface area, and excellent semiconductor properties. This article systematically summarizes and discusses the latest research progress in COF-based materials for photocatalytic H_2O₂ production. First, the fundamental principles of COFs and their application in H_2O₂ photosynthesis are briefly introduced. Then, the main strategies and methods for enhancing photocatalytic performance are comprehensively reviewed and analyzed. Furthermore, the challenges and future prospects of COF-based photocatalysts in visible-light-driven H_2O₂ production are also discussed and summarized.

KeyWords： covalent organic framework; photocatalysis; hydrogen peroxide;

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中图分类号:O644.1;O643.36;TQ123.6

引用信息:

[1]赵斐,谢可慧,王广博,等.共价有机框架材料用于光合成H_2O_2研究进展[J].山东师范大学学报(自然科学版),2025,40(04):325-351.

基金信息:

国家自然科学基金资助项目(22171169)

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山东师范大学学报(自然科学版)

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